As above list plus
If continuing with event, consider what additional mitigations are needed and how these will be communicated to participants where appropriate - note specific risks section below.
http://www.metoffice.gov.uk/public/weather/warnings
https://orienteering.sport/orienteering/internal/event-organising/plan-and-organise-an-iof-event/
IOF interim guidance recommends use of Wet Bulb Globe Temperature (WBGT) to estimate heat risk. This can be estimated from forecast temperature and humidity using the following table.
IOF recommends that organisers of events with expected winning time >20 mins consider cancellation or postponement when the WBGT exceeds 30 °C to 32 °C. For a long event in full sun in exposed terrain, the cancellation threshold is likely to be at the lower end of this range. For a middle distance event in shady forest it may be higher in the range.

If continuing with event, consider what additional mitigations are needed and how these will be communicated to participants where appropriate